Thermosets 2018-06-21T10:27:51+00:00

Thermosets

Thermosetting plastics, also known as thermosets, are plastics that become rigid and nondeformable after hardening. They are one of the three different groups into which polymers can be divided – thermoplastics, elastomers and thermosets – according to thermosetting degree of the macromolecular chains. While thermoplastics have no cross-linking thermosetting points and are therefore fusible, elastomers and thermosets are thermosetting, not fusible, and disintegrate if the decay temperature is exceeded (pyrolysis).

Bakelite, a phenoplastic, was the first thermoset to be industrially produced at the beginning of the twentieth century. Bakelite was invented by Leo Henricus Baekeland a Belgian-American chemist.

Thermosets are rigid vitreous polymer materials three-dimensionally cross-linked by chemical primary valency bonds. The bonds are created when preliminary products chemically react with molecular chains, either at room temperature with the help of catalysts, or thermally activated at high temperatures. The extremely high thermo-mechanical strength of thermosetsprovide excellent electrical properties and exceptional resistance to chemicals due to their high cross-linking density.

Typical applications

These properties define the respective application fields. High-strength thermosets are used for example in the automobile industry for technical components in engine compartments or drive trains, particularly because of their heat resistance under heavy loading. In electrical systems their combined properties of good insulation, positive fire behaviour and indeformability are paramount. Their good resistance to numerous gaseous and liquid media also makes thermosets first choice for the food and chemical industries.

Compounding requirements

Thermosetting polymer production starts by compounding polymer pre-products with glass or carbon reinforcement fibres, fillers or natural fibres. This is followed in many cases by the respective reaction systems for final thermosetting. Gentle incorporation of the additives is just as essential as strict compliance with the absolute temperature limits required for thermosets. . The Buss Kneader handles this perfectly thanks to its harmonic operating principle, with a relaxation phase after each graduated shear stroke. Optimal process temperatures can be verified at all times by precise measurement of the product temperature through hollow-bored kneading bolts fitted with thermocouples at several locations along the processing section. As a result of custom-tailored materials engineering, optimally long service life is typical for thermosetting materials.

Buss Kneader technology is perfectly suited to the compounding of thermosets due to its cost-effective throughput and the numerous advantages of continuous production. These include unwaveringly excellent and reproducible product quality, renown temperature control, optimal
plant utilization and high production yields. After compounding, the thermosets are rolled out and crushed. Some of these products, such as phenoplastics and melamine resins, can also be hot-pelletized. This brings further productivity gains over alternative processing methods.

Together with broadly based Buss process expertise, the Buss Kneader is therefore first choice for continuous thermoset compounding, as witnessed by the numerous plants already installed in this field throughout the world.

Typical plant layout for Thermosets

BUSS compounding systems offer the following specific benefits

  • Low process temperatures
    The separation of mixing in the Buss Kneader and pressure build-up in the discharge unit allows mixing at low pressure and temperature. The requirements of each individual process section are addressed with ingenious screw designs for optimized temperature profiles.

  • Uniform, moderate shear rates
    Uniformly moderate shear rates allow controlled mixing at low-temperatures while imparting only the required shear for the task at hand. The narrow shear rate distribution compared to alternative systems ensures uniform shear histories for every individual particle. This results in high quality compounding with reduced energy input.

  • Precise temperature control
    The Buss Kneader has been well known for precise temperature control since more than 6 decades. This is achieved via controlled energy input due to uniform, moderate shear rates and precise temperature monitoring by thermocouples mounted in pins along the barrel.

  • Intensive mixing at low specific energy input
    Buss multiple-flight Kneaders of the latest generation achieve better mixing at 15-40% lower overall specific energy input. This is because of an increased number of mixing cycles according to the needs of each individual process section. The energy for melting and mixing is provided almost entirely mechanically and optimally dissipated according to the imparted shear rates.

  • Intensive distributive mixing
    The Buss Kneader achieves intensive distributive mixing because the combined rotation and axial motion of the Kneader screw generates extensional flow, a large number of shear interfaces, and cross channel mixing.

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